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Magnetic properties and magnetocaloric effect in the HoNi1-xCuxIn (x=0, 0.1, 0.3, 0.4) intermetallic compounds

Identifieur interne : 000077 ( Main/Repository ); précédent : 000076; suivant : 000078

Magnetic properties and magnetocaloric effect in the HoNi1-xCuxIn (x=0, 0.1, 0.3, 0.4) intermetallic compounds

Auteurs : RBID : Pascal:14-0085416

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Abstract

The magnetic properties and magnetocaloric effect (MCE) in HoNi1-xCuxIn (x=0, 0.1, 0.3, 0.4) compounds have been investigated. With the substitution of Cu for Ni, the Ho magnetic moment will cant from the c-axis, and form a complicated magnetic structure. These compounds exhibit two successive magnetic transitions with the increase in temperature. The large reversible magnetocaloric effects have been observed in HoNi1-xCuxIn compounds around Tord, with no thermal and magnetic hysteresis loss. The large reversible isothermal magnetic entropy change (-ΔSM) is 20.2 J/kg K and the refrigeration capacity (RC) reaches 356.7 J/kg for field changes of 5 T for HoNi0.7Cu0.3In. Especially, the value of -ΔSM (12.5 J/kg K) and the large RC (132 J/kg) are observed for field changes of 2 T for HoNi0.9Cu0.1In. Additionally, the values of RC are improved to 149 J/K for the field changes of 2 T due to a wide temperature span for the mix of HoNi0.9Cu0.1In and HoNi0.7Cu0.3In compounds with the mass ratio of 1:1. These compounds with excellent MCE are expected to have effective applications in magnetic refrigeration around 20 K.

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Pascal:14-0085416

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<name sortKey="He, Xiao Nan" uniqKey="He X">Xiao-Nan He</name>
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<name sortKey="Sun, Ji Rong" uniqKey="Sun J">Ji-Rong Sun</name>
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<name sortKey="Shen, Bao Gen" uniqKey="Shen B">Bao-Gen Shen</name>
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<term>Copper alloys</term>
<term>Holmium alloys</term>
<term>Hysteresis loss</term>
<term>Indium alloys</term>
<term>Intermetallic compounds</term>
<term>Iron loss</term>
<term>Magnetic hysteresis</term>
<term>Magnetic moments</term>
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<term>Thermal hysteresis</term>
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<term>Composition chimique</term>
<term>Effet magnétocalorique</term>
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<div type="abstract" xml:lang="en">The magnetic properties and magnetocaloric effect (MCE) in HoNi
<sub>1-x</sub>
Cu
<sub>x</sub>
In (x=0, 0.1, 0.3, 0.4) compounds have been investigated. With the substitution of Cu for Ni, the Ho magnetic moment will cant from the c-axis, and form a complicated magnetic structure. These compounds exhibit two successive magnetic transitions with the increase in temperature. The large reversible magnetocaloric effects have been observed in HoNi
<sub>1-x</sub>
Cu
<sub>x</sub>
In compounds around T
<sub>ord</sub>
, with no thermal and magnetic hysteresis loss. The large reversible isothermal magnetic entropy change (-ΔS
<sub>M</sub>
) is 20.2 J/kg K and the refrigeration capacity (RC) reaches 356.7 J/kg for field changes of 5 T for HoNi
<sub>0.7</sub>
Cu
<sub>0.3</sub>
In. Especially, the value of -ΔS
<sub>M</sub>
(12.5 J/kg K) and the large RC (132 J/kg) are observed for field changes of 2 T for HoNi
<sub>0.9</sub>
Cu
<sub>0.1</sub>
In. Additionally, the values of RC are improved to 149 J/K for the field changes of 2 T due to a wide temperature span for the mix of HoNi
<sub>0.9</sub>
Cu
<sub>0.1</sub>
In and HoNi
<sub>0.7</sub>
Cu
<sub>0.3</sub>
In compounds with the mass ratio of 1:1. These compounds with excellent MCE are expected to have effective applications in magnetic refrigeration around 20 K.</div>
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<s0>The magnetic properties and magnetocaloric effect (MCE) in HoNi
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In (x=0, 0.1, 0.3, 0.4) compounds have been investigated. With the substitution of Cu for Ni, the Ho magnetic moment will cant from the c-axis, and form a complicated magnetic structure. These compounds exhibit two successive magnetic transitions with the increase in temperature. The large reversible magnetocaloric effects have been observed in HoNi
<sub>1-x</sub>
Cu
<sub>x</sub>
In compounds around T
<sub>ord</sub>
, with no thermal and magnetic hysteresis loss. The large reversible isothermal magnetic entropy change (-ΔS
<sub>M</sub>
) is 20.2 J/kg K and the refrigeration capacity (RC) reaches 356.7 J/kg for field changes of 5 T for HoNi
<sub>0.7</sub>
Cu
<sub>0.3</sub>
In. Especially, the value of -ΔS
<sub>M</sub>
(12.5 J/kg K) and the large RC (132 J/kg) are observed for field changes of 2 T for HoNi
<sub>0.9</sub>
Cu
<sub>0.1</sub>
In. Additionally, the values of RC are improved to 149 J/K for the field changes of 2 T due to a wide temperature span for the mix of HoNi
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Cu
<sub>0.1</sub>
In and HoNi
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