Magnetic properties and magnetocaloric effect in the HoNi1-xCuxIn (x=0, 0.1, 0.3, 0.4) intermetallic compounds
Identifieur interne : 000077 ( Main/Repository ); précédent : 000076; suivant : 000078Magnetic properties and magnetocaloric effect in the HoNi1-xCuxIn (x=0, 0.1, 0.3, 0.4) intermetallic compounds
Auteurs : RBID : Pascal:14-0085416Descripteurs français
- Pascal (Inist)
- Composition chimique, Effet magnétocalorique, Moment magnétique, Transition magnétique, Hystérésis thermique, Hystérésis magnétique, Perte magnétique, Perte watts, Réfrigérateur magnétique, Polycristal, Composé intermétallique, Holmium alliage, Cuivre alliage, Indium alliage, Nickel alliage, Métal transition alliage.
English descriptors
- KwdEn :
- Chemical composition, Copper alloys, Holmium alloys, Hysteresis loss, Indium alloys, Intermetallic compounds, Iron loss, Magnetic hysteresis, Magnetic moments, Magnetic refrigerators, Magnetic transitions, Magnetocaloric effects, Nickel alloys, Polycrystals, Thermal hysteresis, Transition element alloys.
Abstract
The magnetic properties and magnetocaloric effect (MCE) in HoNi1-xCuxIn (x=0, 0.1, 0.3, 0.4) compounds have been investigated. With the substitution of Cu for Ni, the Ho magnetic moment will cant from the c-axis, and form a complicated magnetic structure. These compounds exhibit two successive magnetic transitions with the increase in temperature. The large reversible magnetocaloric effects have been observed in HoNi1-xCuxIn compounds around Tord, with no thermal and magnetic hysteresis loss. The large reversible isothermal magnetic entropy change (-ΔSM) is 20.2 J/kg K and the refrigeration capacity (RC) reaches 356.7 J/kg for field changes of 5 T for HoNi0.7Cu0.3In. Especially, the value of -ΔSM (12.5 J/kg K) and the large RC (132 J/kg) are observed for field changes of 2 T for HoNi0.9Cu0.1In. Additionally, the values of RC are improved to 149 J/K for the field changes of 2 T due to a wide temperature span for the mix of HoNi0.9Cu0.1In and HoNi0.7Cu0.3In compounds with the mass ratio of 1:1. These compounds with excellent MCE are expected to have effective applications in magnetic refrigeration around 20 K.
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Cu<sub>x</sub>
In (x=0, 0.1, 0.3, 0.4) intermetallic compounds</title>
<author><name sortKey="Mo, Zhao Jun" uniqKey="Mo Z">Zhao-Jun Mo</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>School of Material Science and Engineering, Hebei University of Technology</s1>
<s2>Tianjin</s2>
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<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences</s1>
<s2>Beijing</s2>
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<country>République populaire de Chine</country>
<placeName><settlement type="city">Pékin</settlement>
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</author>
<author><name>JUN SHEN</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences</s1>
<s2>Beijing</s2>
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<author><name sortKey="Yan, Li Qin" uniqKey="Yan L">Li-Qin Yan</name>
<affiliation wicri:level="3"><inist:fA14 i1="03"><s1>State Key Laboratory of Magnetism, Beijing National Laboratory for Condensed Matter, Physics and Institute of Physics, Chinese Academy of Sciences</s1>
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<author><name sortKey="Tang, Cheng Chun" uniqKey="Tang C">Cheng-Chun Tang</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>School of Material Science and Engineering, Hebei University of Technology</s1>
<s2>Tianjin</s2>
<s3>CHN</s3>
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<sZ>4 aut.</sZ>
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<author><name sortKey="He, Xiao Nan" uniqKey="He X">Xiao-Nan He</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences</s1>
<s2>Beijing</s2>
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<country>République populaire de Chine</country>
<placeName><settlement type="city">Pékin</settlement>
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<author><name>XINQI ZHENG</name>
<affiliation wicri:level="3"><inist:fA14 i1="03"><s1>State Key Laboratory of Magnetism, Beijing National Laboratory for Condensed Matter, Physics and Institute of Physics, Chinese Academy of Sciences</s1>
<s2>Beijing</s2>
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</placeName>
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</author>
<author><name sortKey="Wu, Jian Feng" uniqKey="Wu J">Jian-Feng Wu</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences</s1>
<s2>Beijing</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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</inist:fA14>
<country>République populaire de Chine</country>
<placeName><settlement type="city">Pékin</settlement>
</placeName>
</affiliation>
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<author><name sortKey="Sun, Ji Rong" uniqKey="Sun J">Ji-Rong Sun</name>
<affiliation wicri:level="3"><inist:fA14 i1="03"><s1>State Key Laboratory of Magnetism, Beijing National Laboratory for Condensed Matter, Physics and Institute of Physics, Chinese Academy of Sciences</s1>
<s2>Beijing</s2>
<s3>CHN</s3>
<sZ>3 aut.</sZ>
<sZ>6 aut.</sZ>
<sZ>8 aut.</sZ>
<sZ>9 aut.</sZ>
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<country>République populaire de Chine</country>
<placeName><settlement type="city">Pékin</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Shen, Bao Gen" uniqKey="Shen B">Bao-Gen Shen</name>
<affiliation wicri:level="3"><inist:fA14 i1="03"><s1>State Key Laboratory of Magnetism, Beijing National Laboratory for Condensed Matter, Physics and Institute of Physics, Chinese Academy of Sciences</s1>
<s2>Beijing</s2>
<s3>CHN</s3>
<sZ>3 aut.</sZ>
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<country>République populaire de Chine</country>
<placeName><settlement type="city">Pékin</settlement>
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<publicationStmt><idno type="inist">14-0085416</idno>
<date when="2014">2014</date>
<idno type="stanalyst">PASCAL 14-0085416 INIST</idno>
<idno type="RBID">Pascal:14-0085416</idno>
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<seriesStmt><idno type="ISSN">0304-8853</idno>
<title level="j" type="abbreviated">J. magn. magn. mater.</title>
<title level="j" type="main">Journal of magnetism and magnetic materials</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Chemical composition</term>
<term>Copper alloys</term>
<term>Holmium alloys</term>
<term>Hysteresis loss</term>
<term>Indium alloys</term>
<term>Intermetallic compounds</term>
<term>Iron loss</term>
<term>Magnetic hysteresis</term>
<term>Magnetic moments</term>
<term>Magnetic refrigerators</term>
<term>Magnetic transitions</term>
<term>Magnetocaloric effects</term>
<term>Nickel alloys</term>
<term>Polycrystals</term>
<term>Thermal hysteresis</term>
<term>Transition element alloys</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Composition chimique</term>
<term>Effet magnétocalorique</term>
<term>Moment magnétique</term>
<term>Transition magnétique</term>
<term>Hystérésis thermique</term>
<term>Hystérésis magnétique</term>
<term>Perte magnétique</term>
<term>Perte watts</term>
<term>Réfrigérateur magnétique</term>
<term>Polycristal</term>
<term>Composé intermétallique</term>
<term>Holmium alliage</term>
<term>Cuivre alliage</term>
<term>Indium alliage</term>
<term>Nickel alliage</term>
<term>Métal transition alliage</term>
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<front><div type="abstract" xml:lang="en">The magnetic properties and magnetocaloric effect (MCE) in HoNi<sub>1-x</sub>
Cu<sub>x</sub>
In (x=0, 0.1, 0.3, 0.4) compounds have been investigated. With the substitution of Cu for Ni, the Ho magnetic moment will cant from the c-axis, and form a complicated magnetic structure. These compounds exhibit two successive magnetic transitions with the increase in temperature. The large reversible magnetocaloric effects have been observed in HoNi<sub>1-x</sub>
Cu<sub>x</sub>
In compounds around T<sub>ord</sub>
, with no thermal and magnetic hysteresis loss. The large reversible isothermal magnetic entropy change (-ΔS<sub>M</sub>
) is 20.2 J/kg K and the refrigeration capacity (RC) reaches 356.7 J/kg for field changes of 5 T for HoNi<sub>0.7</sub>
Cu<sub>0.3</sub>
In. Especially, the value of -ΔS<sub>M</sub>
(12.5 J/kg K) and the large RC (132 J/kg) are observed for field changes of 2 T for HoNi<sub>0.9</sub>
Cu<sub>0.1</sub>
In. Additionally, the values of RC are improved to 149 J/K for the field changes of 2 T due to a wide temperature span for the mix of HoNi<sub>0.9</sub>
Cu<sub>0.1</sub>
In and HoNi<sub>0.7</sub>
Cu<sub>0.3</sub>
In compounds with the mass ratio of 1:1. These compounds with excellent MCE are expected to have effective applications in magnetic refrigeration around 20 K.</div>
</front>
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Cu<sub>x</sub>
In (x=0, 0.1, 0.3, 0.4) intermetallic compounds</s1>
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<fA14 i1="01"><s1>School of Material Science and Engineering, Hebei University of Technology</s1>
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<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
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<fC01 i1="01" l="ENG"><s0>The magnetic properties and magnetocaloric effect (MCE) in HoNi<sub>1-x</sub>
Cu<sub>x</sub>
In (x=0, 0.1, 0.3, 0.4) compounds have been investigated. With the substitution of Cu for Ni, the Ho magnetic moment will cant from the c-axis, and form a complicated magnetic structure. These compounds exhibit two successive magnetic transitions with the increase in temperature. The large reversible magnetocaloric effects have been observed in HoNi<sub>1-x</sub>
Cu<sub>x</sub>
In compounds around T<sub>ord</sub>
, with no thermal and magnetic hysteresis loss. The large reversible isothermal magnetic entropy change (-ΔS<sub>M</sub>
) is 20.2 J/kg K and the refrigeration capacity (RC) reaches 356.7 J/kg for field changes of 5 T for HoNi<sub>0.7</sub>
Cu<sub>0.3</sub>
In. Especially, the value of -ΔS<sub>M</sub>
(12.5 J/kg K) and the large RC (132 J/kg) are observed for field changes of 2 T for HoNi<sub>0.9</sub>
Cu<sub>0.1</sub>
In. Additionally, the values of RC are improved to 149 J/K for the field changes of 2 T due to a wide temperature span for the mix of HoNi<sub>0.9</sub>
Cu<sub>0.1</sub>
In and HoNi<sub>0.7</sub>
Cu<sub>0.3</sub>
In compounds with the mass ratio of 1:1. These compounds with excellent MCE are expected to have effective applications in magnetic refrigeration around 20 K.</s0>
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